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Xiong Zhuang, Wang Su, Zhang Can, Yu Hongru. SHOCK-TUBE EXPERIMENTAL STUDY AND KINETIC MODELING OF JP-10 PYROLYSIS[J]. Chinese Journal of Theoretical and Applied Mechanics, 2019, 51(1): 85-93. doi: 10.6052/0459-1879-18-102
Citation: Xiong Zhuang, Wang Su, Zhang Can, Yu Hongru. SHOCK-TUBE EXPERIMENTAL STUDY AND KINETIC MODELING OF JP-10 PYROLYSIS[J]. Chinese Journal of Theoretical and Applied Mechanics, 2019, 51(1): 85-93. doi: 10.6052/0459-1879-18-102

SHOCK-TUBE EXPERIMENTAL STUDY AND KINETIC MODELING OF JP-10 PYROLYSIS

doi: 10.6052/0459-1879-18-102
  • Publish Date: 2019-01-18
  • Pyrolysis of JP-10 hydrocarbon fuel was studied in a single-pulse shock tube over temperature range from 1150 K to 1300 K. The main decomposition products were identified by gas chromatography as ethylene, acetylene, propylene, $n$-butene, 1,3-butadiene, cyclopentadiene, cyclopentene, benzene, toluene, and a small amount of methane, ethane, xylene and 1-methylcyclopentene. By summation of all product concentrations in each run, the rate coefficient of JP-10 pyrolysis was experimentally determined. Comparative rate measurements were used to eliminate the effects of shock's non-ideality and boundary layer. A small amount of the internal standard compound, whose rate expression for decomposition is well established, was added in the test gas mixtures, and the reaction temperatures were determined according to the decomposition extents of the internal standard compound under the same experimental conditions in a shock tube. The reaction temperatures determined from the decomposition extents of the internal standard compound are usually less than those at the region 5 behind reflected shock calculated by shock velocity measurements. The temperatures determined by two methods are consistent between 1150 K and 1300 K, the difference is within 20 K, and the difference increases with the temperature increase. Based on the experimental study, kinetic modeling of JP-10 pyrolysis was carried out according to San Diego Mechanism. The yields of three main products, ethylene, acetylene and 1,3-butadiene, have a good agreement between the experimental and the simulation results,while the experimental results of cyclopentene yield are much higher than simulation,indicating that both fully and partially ring-opening reactions in JP-10 pyrolysis are important decomposition reaction pathways.

     

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  • [1] Edwards T.Liquid fuels and propellants for aerospace propulsion: 1903-2003. Journal of Propulsion and Power, 2003, 19(6): 1089-1107
    [2] Wickham DT, Engel JR, Rooney S, et al.Additives to improve fuel heat sink capacity in air/fuel heat exchangers. Journal of Propulsion and Power, 2008, 24(1): 55-63
    [3] Gascoin N, Gillard P, Bernard S, et al. Numerical and experimental validation of transient modelling for Scramjet active cooling with supercritical endothermic fuel 4th International Energy Conversion Engineering Conference and Exhibit (IECEC), 2006: 4028
    [4] Zhong Z, Wang Z, Sun M.Effects of fuel cracking on combustion characteristics of a supersonic model combustor. Acta Astronautica, 2015, 110: 1-8
    [5] Zhang C, Qin J, Yang Q, et al.Design and heat transfer characteristics analysis of combined active and passive thermal protection system for hydrogen fueled scramjet. International Journal of Hydrogen Energy, 2015, 40(1): 675-682
    [6] Taddeo L, Gascoin N, Chetehouna K, et al.Experimental study of pyrolysis--combustion coupling in a regeneratively cooled combustor: System dynamics analysis. Aerospace Science and Technology, 2017, 67: 473-483
    [7] 符全军, 燕珂, 杜宗罡等. 吸热型碳氢燃料研究进展. 火箭推进, 2006, 31(5): 32-36
    [7] (Fu Quanjun, Yan Ke, Du Zonggang, et al.Research progress of endothermic hydrocarbon fuels. Journal of Rocket Propulsion. 2005, 31(5): 32-36(in Chinese))
    [8] Bruno TJ, Huber ML, Laesecke A, et al.Thermochemical and thermophysical properties of JP-10. Technical Report NISTIR, 2006, 6640: 325
    [9] Burdette GW, Lander HR, Mccoy JR.High-energy fuels for cruise missiles. Journal of Energy,2012,2(5): 289-292
    [10] Brophy C, Netzer D, Sinibaldi J, et al.Operation of a JP10/air pulse detonation engine//36th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit. 2000: 3591
    [11] Akbar R, Thibault P, Harris P, et al.Detonation properties of unsensitized and sensitized JP-10 and Jet-A fuels in air for pulse detonation engines//36th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit. 2000: 3592
    [12] Cooper M, Shepherd J.Experiments studying thermal cracking, catalytic cracking, and pre-mixed partial oxidation of JP-10//39th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, 2003: 4687
    [13] Herbinet O, Sirjean B, Bounaceur R, et al.Primary mechanism of the thermal decomposition of tricyclodecane. The Journal of Physical Chemistry A, 2006, 110(39): 11298-11314
    [14] Nakra S, Green RJ, Anderson SL.Thermal decomposition of JP-10 studied by micro-flowtube pyrolysis-mass spectrometry. Combustion and Flame, 2006, 144(4): 662-674
    [15] Rao PN, Kunzru D.Thermal cracking of JP-10: Kinetics and product distribution. Journal of Analytical and Applied Pyrolysis, 2006, 76(1): 154-160
    [16] 苏小辉, 侯红梅, 厉刚等. 挂式--四氢双环戊二烯热裂解产物分布研究. 化学学报, 2009, 67(7): 587-592
    [16] (Su Xiaohui, Hou Hongmei, Li Gang, et al.Product distribution of thermal cracking of exo-tetrahydrodicyclopentadiene. Acta Chimica Sinca, 2009, 67(7): 587-592 (in Chinese))
    [17] Chenoweth K, van Duin ACT, Dasgupta S, et al. Initiation mechanisms and kinetics of pyrolysis and combustion of JP-10 hydrocarbon jet fuel. The Journal of Physical Chemistry A, 2009, 113(9): 1740-1746
    [18] 谢文杰, 方文军, 邢燕等. ZSM-5 分子筛催化 JP-10 裂解的研究. 化学学报, 2009, 67(1): 6-12
    [18] (Xie Wenjie, Fang Wenjun, Xing Yan, et al.Catalytic cracking of JP-10 on Zeolite ZSM-5. Acta Chimica Sinica, 2009, 67(1): 6-12(in Chinese))
    [19] Hudzik JM, Asatryan R, Bozzelli JW.Thermochemical properties of exo-tricyclo [5.2. 1.02, 6] decane (JP-10 jet fuel) and derived tricyclodecyl radicals. The Journal of Physical Chemistry A, 2010, 114(35): 9545-9553
    [20] Davidson DF, Horning DC, Oehlschlaeger MA, et al. The decomposition products of JP-10. AIAA Paper, 2001-3707, 2001
    [21] Gaydon AG, Hurle IR.The shock tube in high-temperature chemical physics. Chapman and Hall, 1963: 1-7
    [22] Tsang W, Lifshitz A.Shock tube techniques in chemical kinetics. Annual Review of Physical Chemistry, 1990, 41(1): 559-599
    [23] Tsang W.Comparative rate measurements with a single-pulse shock tube. The Journal of Chemical Physics, 1964, 40(4): 1171-1172
    [24] 范秉诚, 崔季平. 魔洞型单脉冲激波管. 气动实验与测量控制, 1990, 4(3): 58-62
    [24] (Fan Bingcheng, Cui Jiping.Single-pulse shock tube with a magic hole. Aerodynamic Experiment and Measurement & Control, 1990, 4(3): 58-62(in Chinese))
    [25] 崔季平,范秉诚,何宇中.单脉冲激波管在化学动力学研究上的应. 化学物理学报, 1992(5): 374-377
    [25] (Cui Jiping, Fan Bingcheng, He Yuzhong, The application of single pulse shock tube in chemical kinetics studies. Chinese Journal of Chemical Physics, 1992(5):374-377(in Chiinese))
    [26] 勾华杰, 王苏, 范秉诚等. 激波管中测量 JP-10 点火延时的吸附问题研究. 实验流体力学, 2006, 20(4): 69-72
    [26] (Gou Huajie, Wang Su, Fan Bingcheng, et al.Experimental studies of the adsorption in shock tube measurements of the JP-10 ignition delay time. Journal of Experiments in Fluid Mechanics, 2006,20(4): 69-72(in Chinese))
    [27] Tsang W.Comparative rate single-pulse shock tube studies on the thermal decomposition of cyclohexene, 2, 2, 3-trimethylbutane, isopropyl bromide, and ethylcyclobutane. International Journal of Chemical Kinetics, 1970, 2(4): 311-323
    [28] Tsang W, Lifshitz A.Kinetic stability of 1,1,1-Trifluoroethane. International Journal of Chemical Kinetics, 1998, 30(9): 621-628
    [29] Tang W, Brezinsky K.Chemical kinetic simulations behind reflected shock waves. International Journal of Chemical Kinetics, 2006, 38(2): 75-97
    [30] Li SC, Varatharajan B, Williams FA.Chemistry of JP-10 ignition. AIAA Journal, 2001, 39(12): 2351-2356
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