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NiTi合金相变斑图演化的应变率依赖性研究

RESEARCH ON THE STRAIN RATE DEPENDENCE OF PHASE TRANSFORMATION PATTERN EVOLUTION IN NITI ALLOYS

  • 摘要: NiTi合金在非等温加载下产生强烈的非线性热耦合相变,伴随着丰富的相界面斑图变化,这种独特的现象与界面厚度和应变率相关。外部驱动应变率增加到一定程度可能会打破传统的等温成核生长模式,而此前尚未被研究过。本工作通过高速摄像技术和数字图像相关法,观测了不同应变率下多种厚度的纳米态NiTi多晶条带的相变斑图演化。基于Ginzburg-Landau理论,引入界面尺度和潜热释放传导的时间尺度,建立动量平衡方程和热方程,采用摄动分析研究相变初期斑图形成与演化。与传统恒定外部场系统不同,本驱动系统扰动分析更具挑战性,其均匀基底持续变化且考虑驱动率时间尺度。结果表明:临界应变率由界面厚度决定,相变早期斑图波长与应变率呈-1/6幂律关系,超过临界应变率则斑图形成被抑制,相变均匀生长。相变后期斑图演化为有序的成核和畴生长,其特征畴间距与应变率呈-1/2幂律关系。相变模式从低速率的失稳成核生长转变为高速率的自发生长,体现了热力耦合下成核生长模式的崩溃。

     

    Abstract: NiTi alloys exhibit a pronounced nonlinear thermomechanical coupling during phase transition under non-isothermal loading conditions, accompanied by a variety of interfacial pattern changes. This unique phenomenon is related to the interface thickness and strain rate. When the applied strain rate increases to a certain level, it may disrupt the traditional isothermal nucleation and growth, which has not been previously studied. In this work, we observed the evolution of transformation patterns in nanocrystalline NiTi polycrystalline strips with different thicknesses under various strain rates, using high-speed camera technology and digital image correlation. Based on the Ginzburg-Landau theory, we introduced the interface scale and the time scale of latent heat release and conduction, established the momentum balance equation and heat equation, and used perturbation analysis to study the formation and evolution of patterns in the early stage of phase transition. Unlike traditional systems with constant external fields, the perturbation analysis of our driving system is more challenging, with a continuously changing uniform substrate and consideration of the time scale of the driving rate. The results show that the critical strain rate is determined by the interface thickness. In the early stage of phase transition, the pattern wavelength follows a -1/6 power-law relationship with the strain rate. When the strain rate exceeds the critical value, pattern formation is suppressed, and the phase transition grows uniformly. In the later stage of phase transition, the patterns evolve into ordered nucleation and domain growth, with the characteristic domain spacing following a -1/2 power-law relationship with the strain rate. The phase transition mode shifts from unstable nucleation and growth at low strain rates to spontaneous growth at high strain rates, reflecting the breakdown of the nucleation and growth paradigm under thermomechanical coupling.

     

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