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中文核心期刊

球形水合物颗粒对流换热分解实验研究

EXPERIMENTAL SDUDY ON SPHERICAL HYDRATE PARTICLES DECOMPOSITION UNDER CONVECTIVE HEAT TRANSFER

  • 摘要: 深海海底甲烷泄露及其环境影响评价是进行天然气水合物(简称水合物)开发必须关注的问题之一。甲烷从海床进入海水后,由于浮力作用而向上运动,形成气液固多相流动,伴随着水合物壳生成、水合物分解、甲烷溶解、微生物厌氧氧化等多个物理化学过程。纯水合物在对流换热条件下的分解相变速率是海水中甲烷运移评估的关键参数。本文设计了纯水合物颗粒分解相变实验装置,观测不同尺寸的水合物颗粒在不同水体温度、不同水流速度下的分解过程,通过实验探究对流换热条件下水合物分解的机理。基于实验结果分析水合物颗粒的实时分解速率及其变化规律,通过量纲分析方法给出决定分解时间的无量纲控制参数,拟合出对流换热条件下水合物分解时间的无量纲表达式。研究表明,对流换热使水合物颗粒的分解相变明显加快,分解相变时间随雷诺数呈现指数型衰减,随水浴温差呈现幂次型衰减、并且幂指数大于1.0;对流条件的增强,使分解相变阵面有稳定推进的趋势。希望本文研究得到的结果为甲烷泄露环境评价、新型开采方案的可行性论证提供基础参数。

     

    Abstract: The methane leakage in deep seabed and its environmental affection assessment is one of the important problems considered in the development of natural gas hydrate. After entering into seawater, the methane moves upward due to buoyancy and forms gas-liquid-solid multiphase flow, accompanied by physical and chemical processes such as hydrate shell formation, hydrate decomposition, methane dissolution and microbial anaerobic oxidation. The decomposition and phase transition rate of pure hydrate under convective heat transfer is a key parameter to evaluate methane migration in seawater. In this article, a new device for hydrate particles decomposition phase change is accomplished which can control the temperature and velocity of flowing water, then the decomposition process of different hydrate particle sizes under different water temperatures and flowing velocities are recorded, formulating the mechanism of decomposition of hydrate affected by convection heat transfer. Based on experiments the real time decomposition rate of hydrate particles and its variation law is analyzed and by dimensional analysis method key variables determining the decomposition time are deduced, then the general dimensionless expression of the hydrate decomposition time under convective heat transfer is obtained by mathematical fitting. The results show that, convective heat transfer accelerates the decomposition phase transition and the decomposition phase transition time decays exponentially with Reynolds number, as power function with temperature difference and the power index is greater than 1.0, then the front of decomposition phase change tends to advance steadily with the enhancement of convection. The results can provide some basic parameters for the environmental assessment of methane leakage and the feasibility argumentation of new mining schemes.

     

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