EI、Scopus 收录
中文核心期刊

由Bezier曲线构造的聚合物熔体剪切黏度模型

A SHEAR VISCOSITY MODEL OF POLYMER MELT CONSTRUCTED BY BEZIER CURVE

  • 摘要: 为提高聚合物熔体剪切黏度模型的描述精度,提出了一个基于二次Bezier 曲线的黏度模型. 模型采用分段函数描述,在对数坐标系中,低剪切速率时的牛顿区和高剪切速率时的幂律区采用线性函数,介于二者之间的过渡区采用二次Bezier 曲线. 通过牛顿区和幂律区的直线延长线构造Bezier 曲线的控制多边形,从而保证三段曲线的光滑过渡. 模型可以明确给出任意温度下低剪切速率时牛顿区的结束点,以及高剪切速率时幂律区的开始点. 拟合算例表明,所提出模型的拟合精度明显高于Cross-Arrhenius 黏度模型.

     

    Abstract: A shear viscosity model of polymer melt is proposed based on a quadric Bezier curve to improve the model's descriptive precision. The model is characterized by piecewise functions in a logarithmic coordinate. Linear functions are adopted to represent the two linear sections of the Newton region at lower shear rates and the power law region at higher shear rates. A quadric Bezier curve is applied to describe the transitional region between the two linear regions. The three curves are connected smoothly by a control polygon which is formed through the extension lines of the two linear curves of the Newton region and the power law region. At any temperature, the end point of the Newton region at lower shear rates and the start point of the power law region at higher shear rates are predicted accordingly. The data fitting examples show that the precision of the proposed model turns out to be obviously higher than that of the Cross-Arrhenius model.

     

/

返回文章
返回